Rhenium-Catalyzed Formation of Indene Frameworks via C—H Bond Activation: [3 + 2] Annulation of Aromatic Aldimines and Acetylenes.
نویسندگان
چکیده
منابع مشابه
Rhenium-catalyzed synthesis of indene derivatives via C–H bond activation*
Rhenium complex, [ReBr(CO)3(thf)]2-catalyzed reactions between aromatic imines and either acetylenes or α,β-unsaturated carbonyl compounds gave indene derivatives in good to excellent yields. These reactions proceed via C–H bond activation, insertion of acetylenes or α,β-unsaturated carbonyl compounds, intramolecular nucleophilic cyclization, and reductive elimination. Indene derivatives were a...
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ژورنال
عنوان ژورنال: ChemInform
سال: 2006
ISSN: 0931-7597,1522-2667
DOI: 10.1002/chin.200604092